Actually that wouldn't make crystals. Crystals form by accreting water vapor in the surrounding air, which would take too long to make in a freezer using spray.
In fact, if you sprayed a fine mist into a freezer, you'd only end up with a fine coating of ice on the surfaces. Liquid droplets of water are notoriously difficult to freeze unless they come in contact with something. (Note freezing rain).
But to answer Karajorma's first question, I don't see any reason why the superglue-technique wouldn't work with the crystals in a freezer. Should be worth giving a try.
