All of the WAV files are in the various .VP archives depending on what the particular WAV is used for. The Underdogs version has the files extracted which causes various problems, including crashes and excessive CPU usage from 0 byte anis, with the Linux and therefore the OSX version. The icculus.org code is not going to be modified to make the Underdogs version work correctly so please don't ask.
Movies need to go in Data/Movies (may or may not be case sensitive) in order to be played with the current player code. The new code, that I haven't finished the audio on yet, uses CFILE to locate the movies in all directories that CFILE manages, including the CD-ROM. As soon as I get the movie audio to stream correctly it will be added to CVS.
Briefing voices and music don't work yet in the icculus.org code. The decoder for the sound data is there but I haven't finished the streaming code and plugged it all together yet. I haven't had much time to work on it over the past month but I plan to get back to it this month so working code should be available soon. When it is done the streaming code will be added to FSO as well.