Ah, let's be mathematic-philosophical then.
I think we can consider human consciense as restricted entity, yes? So, this in itself defines a maximum value of "priceless", thus making it smaller than mathematical constant known as "infinity".
Thus, if we mark "priceless" as "p", we end up with following unequation:
1*p < 5*p | (...) / p
note that becuse we just defined "priceless" being "non-infinite" due to limitations of human mind, "p"s contract off and the equation shows us that
1<5
which is, frankly, true.
Even if we want to view "priceless" as "infinity", we can take on the concept of Limes, which helps to understand this kind of things.
Let us say that a value of life closes the infinity without limits. Thus, a value of life is
V = Lim x
x->Infinity
Thus, comparision can be made:
1 V < 5 V
Lim x < 5*Lim x
x->Infinity x->Infinity
Here we can see that whereas x does get closer and closer to infinity, the comparision can still be made because regardless of how high the curve gets, 5 times almost infinity is more than almost infinity. Thus, five lifes is more valuable, even if a value of a single life would close infinity without bounds.
If, however, we take a position of a hypothetical God observing the situation and for some reason feeling intereted enough to compare the values of five lifes to a single life, he'd probably take one glance, define the value of human life from His viewpoint as infinitely small, closing to zero, and form a following equation:
V = Lim 1/x
x->Infinity
Lim 1/x < 5 *Lim 1/x
x->Infinity x->Infinity
Even at this case, we notice that even when the value of a life observed from God's viewpoint closes zero without limits, at certain given value five times the value is still greater than the value itself.
So, mathematically and philosophically it is insufficient to say that 5 times infinite is infinite, because human mind doesn't comprehend infinities well enough to handle them properly without help of Limes, the magical thing that enagbles the differential equations to work and other nice stuff like that. Nice little thing it is.
Anyway, 5 lifes > 1 life, Quod Erat Demonstrandum.

Kie: The Fat Man would certainly block the trolley (what kinda crap light trolley is that? How would I ever manage to heave a fat enough man to
stop a frickin' trolley to the track in the first place?), but there can not be certainty about the five people dying. Except in a think test.