I'm tempted to perma-ban anyone who uses DreamWeaver.

I gotta side with an0n on this one - at least as far as the webdev tools are concerned. I code everything by hand, using NotePad++, or TopStyle, or a combo of both. I also work nearly exclusively with CMSes, such as the aforementioned MODx, or my current preference,
ExpressionEngine, which allows me total control over the design and code produced.
As for the process I go through, usually I have a design done up in Photoshop, which I then convert to HTML+CSS bit by bit. That skeleton HTML template then gets sliced up into modular, reusable parts according to whichever CMS I'm using. I end up inserting the content-pulling tags into the resulting templates, tying it all together.