Your info's a bit off, Nuke...
Diamonds are actually the best conductors of heat available, I believe. However, they do not conduct electricity. Gotta love those non-metals (carbon, but everyone knows that).
Silver is the best conductor of electricity as far as my knowledge goes... I've not had the ambient temperature scenario as an argument before, but silver is indeed the best conductor of electricty as far as I'm aware. Now, this isn't to say temperature isn't a factor, as most superconductors (zero - nil resistance means awesome conductance...) become that way when the given element is brought down to near zero-Kelvin numbers (absolute zero). However, that's friggin' cold and you're not going to have that as a factor in your everyday job... Unless you work at a university/lab with a superconducting magnet.
Copper is second-best by a small margin. It's fairly common and much more common than silver. If you've got all-silver electronics, you've got way too much cash on hand.
I'm not sure how gold and platinum stack up, but the main attractions are that the metals are basically inert - they don't corrode. It appears that platimum has a rather low expansion coefficient, so it's valuable in high-temperature situations.
Lastly, I didn't mean to offend you, pecenipicek. I apologise if I did.